Can't go wrong with copper, but it's expensive. When I plumbed my shop for air I used polyethylene tubing (rated 190 psi in the 1/2" OD size) and nylon compression tees and elbows (rated 200 psi). It was the cheapest stuff McMaster had that was rated for the pressure (I run my compressor at 120psi). At the ends I clamped a 6" galvanized pipe nipple to the shop rafters with a quick disconnect coupling on the bottom and the compression fitting for the tubing on the top.
PVC pipe is a bad idea for an air system... while it's rated for the pressure, it's brittle so it fatigues if the pressure fluctuates a lot, i.e. if you don't leave the system pressurized so it goes to zero often.