Will it work?
NO CLUE!
The drawing is very simple, the 120 vac goes at the bottom and the switching as on the side.
Not wanting to be disrespectful, but if you need help figuring out how to connect this relay, and you are working with 120 volts...STOP.
There is not enough information to state if it will work, apply 120 vac to the coil and the relay switches.
What controls the voltage to the relay?
What does the relay control?
Stop a motor?
How is the motor controlled?
What type?
It seems simple to have the relay in series with motor power, but depending on how the motor is controlled, there may be different ways.
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