Thanks for the lead. I may have to give it a try. I see that Home Depot sells them.
From the MSDS, it looks like the ingredients are the same as for black powder with possibly an inhibitor to provide a slow burn rather than an explosion. The MSDS states tha oxides of sulfur are produced when burning. These would be sulfur dioxide and sulfur trioxide. Sulfur dioxide is a gas sometimes used to bleach cherries to make Maraschino cherries. It combines with water to make sulfurous acid which reacts with metal oxides to make sulfites. Sulfur trioxide combines with water to make sulfuric acid. When I worked in a chem lab tears ago, we used to digest samples in sulfuric acid on a hot plate. As the water was driven off, dense white clouds of sulfur trioxide would form and even though we were operating in a fume hood, some of the fumes would escape into the lab. If carbon monoxide is being produced, almost certainly carbon black is in the formula. Sodium nitrate is listed as 50 -75% of the ingredients in the MSDS.
Over the years, I have breathed in more than my share of sulfur dioxide and sulfur trioxide, the former with my Gilbert chemistry set as a lad and the latter working as a chemist. Obnoxious but not particularly lethal. Professional exterminators will use hydrogen cyanide which is considerably more deadly. Levels of more than 100 ppm cause death in a few hours; over 200 ppm, in a few minutes.
Hydrogen sulfide (rotten egg smell) is as lethal as cyanide. It's only saving grace, if any, is that no one can stand to be in an area with a lethal amount long enough to succumb to it. It can be produced by heating sulfur and paraffin. One of my early chemistry experiments. It took forever to air out my bedroom. At the time, I wasn't aware of its toxicity. In chemistry qualitative analysis lab in college, we used a hydrogen sulfide generator to precipitate various metal salts. Again we had no idea of its toxicity, just that the smell was obnoxious. There was no such thing as an MSDS in those days.
A potential DIY fumigator would be to heat a closed vessel containing paraffin and sulfur with a tube leading into mole tunnel. The reaction stops when heat is removed. As long as you had a good breeze blowing it should be safe. The neighbors might not appreciate it though and I have no idea as to how long the odor would remain.
Pouring ammonia into a burrow or tunnel should also work. I expect that it would be more a repellent than a poison though. The plus is the it is a good soil nutrient.