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I would guess that the rock involved contain metallic elements. Elements like sodium, lithium, and potassium react rather violently with water at room temperature to produce hydrogen. At elevated temperatures, magnesium reacts with water to produce hydrogen, As you go down the electromotive series, the reactions become less violent but they still happen.
When water is exposed to metallic elements deep in the earth where high temperatures and pressure occur, it is feasible that an appreciable amount of hydrogen gas could be generated.
When water is exposed to metallic elements deep in the earth where high temperatures and pressure occur, it is feasible that an appreciable amount of hydrogen gas could be generated.